Smile.JPG.cat: JPEG image data, JFIF standard 1.01
There is nothing wrong with the file, and it opens fine on my computer. You're probably just using a bogus operating system that assumes the filename extension corresponds to the actual file type. I have no idea how you managed to screw that up, but rename the file Smile.cat.jpg and it will work (in Windows, you'll need to disable "Hide extensions for known file types" like Avan said (although in Windows 7, Folder Options is no longer in the Control Panel, it's in a Windows Explorer -> Tools (you also need to press Alt to see the menu for some dumb reason)).