May not be Mylo's thing, But LotR is mine, along with Koji Kondo and Zelda Reorchestrated's stuff. Got some Hans Zimmer in the playlist, but it's not my top. Concerning Hobbits, The Hornburg, Return of the King, Koji Kondo's Gerudo Valley and Twilight Princess Symphonic Movement, and Zreo's Midna Suite, Majora's Mask tunes and Windmill Hut are probably my favourites. Also Roxanne from Moulin Rouge should get a mention.
EDIT: Totally forgot Pink Floyd's The Wall. The Trial, Comfortably Numb, Waiting for the Worms and Empty Spaces are quite splendid